Maria Sharapova RUS (1) vs. Evgeniya Rodina RUS
Q-Bethanie Mattek USA vs. Madison Brengle USA
Q-Jarmila Gajdosova SVK vs. Olivia Sanchez FRA
Martina Muller GER vs. Karin Knapp ITA (32)
Maria Kirilenko RUS (21) vs. Maria Elena Camerin ITA
Q-Jie Zheng CHN vs. Mara Santangelo ITA
Q-Magdalena Rybarikova SVK vs. Karolina Sprem CRO
Kateryna Bondarenko UKR vs. Dinara Safina RUS (13)
Vera Zvonareva RUS (11) vs. Stephanie Foretz FRA
Ioana Raluca Olaru ROU vs. Stephanie Cohen-Aloro FRA
Q-Yanina Wickmayer BEL vs. Akgul Amanmuradova UZB
Aleksandra Wozniak CAN vs. Sybille Bammer AUT (20)
Ai Sugiyama JPN (31) vs. Alla Kudryavtseva RUS
Olga Govortsova BLR vs. Yuliana Fedak UKR
Marta Domachowska POL vs. Rossana De Los Rios PAR
Vera Dushevina RUS vs. Elena Dementieva RUS (7)