Justine Henin BEL (1) vs. Aiko Nakamura JPN
Monique Adamczak AUS vs. Olga Poutchkova RUS
Maret Ani EST vs. Angelique Kerber GER
Emilie Loit FRA vs. Francesca Schiavone ITA (25)
Sybille Bammer AUT (19) vs. Q-Tamarine Tanasygarn THA
Q-Su-Wei Hsieh TPE vs. Klara Zakopalova CZE
Kateryna Bondarenko UKR vs. Aravane Rezai FRA
Stephanie Cohen-Aloro FRA vs. Tatiana Golovin FRA (13)
Elena Dementieva RUS (11) vs. Tzipora Obziler ISR
Anabel Medina Garrigues ESP vs. Petra Cetkovska CZE
Jessica Moore AUS vs. Julie Ditty USA
Renata Voracova CZE vs. Shahar Peer ISR (17)
Julia Vakulenko UKR (32) vs. Elena Vesnina RUS
Jill Craybas USA vs. Yung-Jan Chan TPE
Lindsay Davenport USA vs. Sara Errani ITA
Jelena Kostanic Tosic CRO vs. Maria Sharapova RUS (5)