[化学] 热力学

楼主: essential35 (essential)   2016-09-15 01:31:40
想问几道题。
1、在与外界隔离系统中,假设一块温度为100。C重量50g的银(比热=0.2350J/g。C),
和温度为0。C重量50g的铁块(比热=0.4494J/g。C)放置接触在一起,最后两块金属的
温度为何?
(a)将高于50。c (b)将低于50。C (c)恰好为50。c (d)无法预测
我写的是d,不知道对不对
2、What is the Cp(the molar heat capacity) of a gas which Cv=48J/mol.K at 298K?
这题不知道从何下手。会用到杜龙-博蒂定律吗?想请教一下这个定律是怎么一回事。
3、A gas absorbs 100J of heat and is simultaneously compressed by a constant
external pressure of 1.5 atm from 8.0 to 2.0L in volume. What is <|U in Joules
for the gas.
(a)-812 (b)+812 (c)-912 (d)+912 (e)1012
4、30。C下,某理想气体5.0mol 具有20L 体积,当进行可逆压缩时,放出热量为
5.82*10(11次方)erg,试问其最终体积为:
(a)0.0394 (b)0.0287 (c)0.1970 (d)0.0788 L
我写A,不知道对不对。
希望各位可以帮我,感激不尽。
作者: guitarspirit (e^ipi=-1)   2015-04-05 09:07:00
1.系统是铁和银且由题意可知From 1st law ΔU=Q+W=ΔU(Fe)+ΔU(Ag)=0m(Fe)*C(Fe)*(Tf-T(Fe))+m(Ag)*C(Ag)*(Tf-T(Ag))=02. For ideal gas Cp=Cv+R3.For expansion of an ideal gas at constant PFrom 1st law ΔU=Q-P(Vf-Vi)4. For compression of an ideal gas at constant TFrom 1st law Q=nRTln(Vf/Vi)

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