Caroline Wozniacki DEN (1) vs. Gisela Dulko ARG
Tamira Paszek AUT vs. Vania King USA
Lucie Hradecka CZE vs. Alberta Brianti ITA
Angelique Kerber GER vs. Dominika Cibulkova SVK (29)
Yanina Wickmayer BEL (21) vs. Jarmila Groth AUS
Polona Hercog SLO vs. Anastasija Sevastova LAT
Vesna Manasieva RUS (Q) vs. Laura Pous-Tio ESP
Tathiana Garbin ITA vs. Marion Bartoli FRA (15)
Justine Henin BEL (11) vs. Sania Mirza IND (Q)
Jamie Hampton USA (Q) vs. Elena Baltacha GBR
Bethanie Mattek-Sands USA vs. Arantxa Rus NED (Q)
Alison Riske USA vs. Svetlana Kuznetsova RUS (23)
Tsvetana Pironkova BUL (32) vs. Pauline Parmentier FRA
Timea Bacsinszky SUI vs. Monica Niculescu ROU
Rebecca Marino CAN vs. Junri Namigata JPN
Arantxa Parra Santonja ESP vs. Francesca Schiavone ITA (6)