[1] Novak Djokovic (SRB) - [Q] Conor Niland (IRL)
Pere Riba-Madrid (ESP) - Carlos Berlocq (ARG)
Potito Starace (ITA) - Michael Berrer (GER)
Nikolay Davydenko (RUS) - [32] Ivan Dodig (CRO)
[22] Alexandr Dolgopolov (UKR) - Frederico Gil (POR)
Kei Nishikori (JPN) - Flavio Cipolla (ITA)
Ivo Karlovic (CRO) - Fernando Gonzalez (CHI)
Sergiy Stakhovsky (UKR) - [13] Richard Gasquet (FRA)
[9] Tomas Berdych (CZE) - [Q] Romain Jouan (FRA)
Fabio Fognini (ITA) - Horacio Zeballos (ARG)
Philipp Petzschner (GER) - Albert Ramos-Vinolas (ESP)
[Q] Augustin Gensse (FRA) - [20] Janko Tipsarevic (SRB)
[31] Marcel Granollers (ESP) - Xavier Malisse (BEL)
Mikhail Kukushkin (KAZ) - Albert Montanes (ESP)
Pablo Andujar (ESP) - Juan Carlos Ferrero (ESP)
Grigor Dimitrov (BUL) - [7] Gael Monfils (FRA)