Rafael Nadal ESP (1) vs. Christophe Rochus BEL
Florent Serra FRA vs. Roko Karanusic CRO
Eduardo Schwank ARG vs. Tommy Haas GER
Q-Flavio Cipolla ITA vs. Dmitry Tursunov RUS (29)
Richard Gasquet FRA (24) vs. Diego Junqueira ARG
Vincent Spadea USA vs. Denis Istomin UZB
Guillermo Canas ARG vs. Q-Dieter Kindlmann GER
Lleyton Hewitt AUS vs. Fernando Gonzalez CHI (13)
Gael Monfils FRA (12) vs. Martin Vassallo Arguello ARG
Mikhail Youzhny RUS vs. Stefan Koubek AUT
Andrey Golubev KAZ vs. Fabio Fognini ITA
Nicolas Massu CHI vs. Nicolas Almagro ESP (17)
Ivo Karlovic CRO (25) vs. Daniel Gimeno-Traver ESP
Q-Wayne Odesnik USA vs. Mario Ancic CRO
Chris Guccione AUS vs. Nicolas Devilder FRA
Pablo Andujar ESP vs. Gilles Simon FRA (6)