与男单一样，有九位亚洲选手参加2023澳网女单会外赛，分布在八个小区，
同样日本选手人数最多，有四位。
[3] Anna Karolína Schmiedlova VS. Irina Khromacheva RUS
Jessika Ponchet FRA vs. Katie Swan GBR
Marcela Zacarías MEX vs. 本玉真唯 JPN
Sonay Kartal GBR vs. [21] Elizabeth Mandlik USA
[4] Cristina Bucsa ESP vs. [WC] Kaylah McPhee AUS
Ashlyn Krueger USA vs. [PR] Eugenie Bouchard CAN
Mirjam Björklund SWE vs. Ekaterina Reyngold RUS
Louisa Chirico USA vs. [32] 日比野菜绪 JPN
[7] Sara Errani ITA vs. 蒋苏晶 KOR
Hailey Baptiste USA vs. Yuriko Miyazaki GBR
Petra Marcinko CRO vs. Mona Barthel GER
[PR] Arina Rodionova AUS vs. [23] CoCo Vandeweghe USA
[8] Diana Shnaider RUS vs. Joanne Zuger SWI
Maria Carle ARG vs. Robin Montgomery USA
Anastasia Tikhonova RUS vs. Suzan Lamens NED
韩娜梨 KOR vs. [28] Viktória Kueghe SLO
[9] Léolia Jeanjean FRA vs. Irina Bara ROM
Kayla Day USA vs. Ekaterina Makarova RUS
Aliona Bolsova ESP vs. Heather Watson GBR
内藤祐希 JPN vs. [31] Lesia Tsurenko UKR
[10] Réka Luca Jani HUN vs. Despina Papamichail GRE
Carolina Alves BRA vs. Olga Danilovic SRB
Carol Zhao CAN vs. 张玮恒 HKG
Elsa Jacquemot FRA vs. [17] Clara Burel FRA
[11] Katie Volynets USA vs. Ekaterine Gorgodze GEO
Leyre Romero Gormaz ESP vs. Nigina Abduraimova UZB
Kristina Mladenovic FRA vs. Maddison Inglis AUS
Valentini Grammatikopoulou GRE vs. [18] Marina Bassols Ribera ESP
[14] Laura Pigossi BRA vs. Magali Kempen BEL
土居美咲 JPN vs. Alex Eala PHI
Ipek Oz TUR vs. [WC] Destanee Aiava AUS
Arianne Hartono NED vs. [19] Ylena In-Albon SUI