[1] Novak Djokovic (SRB) v Qualifier
Marinko Matosevic (AUS) v Carlos Berlocq (ARG)
Jurgen Melzer (AUT) v Pablo Andujar (ESP)
Guillermo Garcia-Lopez (ESP) v [6] Alexandr Dolgopolov (UKR)
[4] Marin Cilic (CRO) v [WC] Marius Copil (ROU)
Florian Mayer (GER) v Fabio Fognini (ITA)
[WC] Ze Zhang (CHN) v [WC] Di Wu (CHN)
Qualifier v [5] Richard Gasquet (FRA)
[7] Tommy Hass (GER) v Mikhail Youzhny (RUS)
Qualifier v Kevin Anderson (RSA)
Nikolay Davydenko (RUS) v Qualifier
Denis Istomin (UZB) v [3] Jo-Wilfried Tsonga (FRA)
[8] Fernando Verdasco (ESP) v Sam Querrey (USA)
Julien Benneteau (FRA) v Andreas Seppi (ITA)
Ryan Harrison (USA) v Feliciano Lopez (ESP)
Yen-Hsun Lu (TPE) v [2] David Ferrer (ESP)