[1] Novak Djokovic SRB v Juan Carlos Ferrero ESP
Ryan Harrison USA v Yen-Hsun Lu TPE
Benjamin Becker GER v James Blake USA
Sergiy Stakhovsky UKR v [28] Radek Stepanek CZE
[24] Marcel Granollers ESP v Viktor Troicki SRB
Martin Klizan SVK v Juan Ignacio Chela ARG
Jeremy Chardy FRA v Filippo Volandri ITA
Leonardo Mayer ARG v [15] Juan Monaco ARG
[12] Nicolas Almagro ESP v Rochus BEL
[Q] Guillaume Rufin FRA v Steve Darcis BEL
Carlos Berlocq ARG v [Q] Ruben Bemelmans BEL
Tobias Kamke GER v [18] Richard Gasquet FRA
[31] Florian Mayer GER v Dmitry Tursunov RUS
Philipp Petzschner GER v Blaz Kavcic SLO
[Q] Simone Bolelli ITA v [Q] Jerzy Janowicz POL
Ernests Gulbis LAT v [6] Tomas Berdych CZE